He first appeared in a backup story in Captain America where the Schutz Heiliggruppe captured the Red Skull and abducted him back to Germany in an attempt to put him on trial for war crimes.
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Although they captured the Skull and subsequently his Skeleton Crew, they later surrendered the Skull to a false Thor, Iron Man and Captain America, who were actually shapeshifting "bioplastoid" androids created by the Skull's lackey Arnim Zola.
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