She came to Poland at the age of five years as a lady in waiting to Marie Louise Gonzaga, the French-born Queen of Poland from 1645 to 1672, wife and consort to two Polish kings — Władysław IV Vasa and later his brother (who succeeded him) John II Casimir Vasa.
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She was the eldest child and only daughter of John II Casimir Vasa, King of Poland and Grand Duke of Lithuania, by his wife Marie Louise Gonzaga.