In the interval between the first occupation of Paris and the Hundred Days, Müffling served as chief of the staff to the Russian General Michael Andreas Barclay de Tolly and to General Friedrich Graf Kleist von Nollendorf.
In 1809 he won a European reputation by a rapid and daring march over the frozen Gulf of Bothnia, which allowed him to surprise the enemy and seize Umeå in Sweden.
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