The two girls playing hopscotch on the sidewalk are Larry Fine's daughter, Phyllis (who died in 1989 at age 60) and Moe Howard's daughter, Joan.
The first short that featured a pie fight of sorts was in Pop Goes the Easel, in which sculptor's clay is thrown at unsuspecting targets.
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He appeared with Peter Blake, Pauline Boty and Peter Phillips in Pop Goes the Easel (1962), a film by Ken Russell for the BBC's Monitor series.