He married for a second time to Princess Maria Immaculata of Bourbon-Two Sicilies, fourth child and eldest daughter of Prince Alfonso of Bourbon-Two Sicilies, Count of Caserta and his wife Princess Antonietta of Bourbon-Two Sicilies, on 30 October 1906 in Cannes, France.
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From 1902, Johann Georg resided at Schloss Weesenstein approximately 30 km from Dresden, high above Müglitztal.
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