From the village it is possible to observe the Bisenzio valley and the villages of Cavarzano San Quirico d'Orcia.
The frazione of Vignoni houses a castle, a residence of the Salimbeni in the 12th century.
The Apennines are the northern border of the phenomenon, and while a definite southern border has not been established, it is present in Siena and further south, through at least San Quirico d'Orcia.
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Montegiovi is about 50 km from Grosseto and 5 km from Castel del Piano, and it is situated on a hill in the western limit of Val d'Orcia.