She joined the BBC's Breakfast programme in 12 January 2001 as a relief presenter, initially presenting on Friday-Sunday alongside Darren Jordon, to cover for main presenter, Sarah Montague, and then later with Jeremy Bowen, to cover for Sophie Raworth.
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Williams, a recreational runner, suffered from hyponatraemia during the 2001 New York City Marathon and spent several days recovering in the hospital.
John Williams | Robin Williams | Robbie Williams | Tennessee Williams | Williams College | Ralph Vaughan Williams | Ted Williams | Vanessa L. Williams | William Carlos Williams | Hank Williams, Jr. | Hank Williams | Don Williams | Williams | Shirley Williams | Lucinda Williams | Andy Williams | Victoria Williams | Serena Williams | Brian Williams | Vanessa Williams | Esther Williams | Paul Williams | Bert Williams | Rowan Williams | Hype Williams | Wendy O. Williams | Michael K. Williams | John Williams (composer) | Clough Williams-Ellis | Williams-Sonoma |
Many reporters and producers have spent some time working on the programme including Sue MacGregor, Kirsty Wark, Charlie Lee-Potter, Ted Harrison, Jonathan Dimbleby, Roger Cook, George Alagiah, Jenny Abramsky, Roger Hearing, Sian Williams, Peter Biles, Kirsty Lang, Martin Fewell, Shelagh Fogarty, David Jessel, Nick Ross, Ben Bradshaw, Juliet Bremner, Susannah Simons, Pallab Ghosh and Martha Kearney.