At Wachau, during the Battle of Leipzig, his corps along with François Étienne de Kellermann's IV Cavalry Corps and the dragoons of the Guard charged the center of Duke of Württemberg.
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On the arrest of the king and the royal family during the Flight to Varennes, Barnave was one of the three appointed to conduct them back to Paris, along with Jerome Petion and the Marquis de Latour-Maubourg.
In 1831, at the consistory that elected Pope Gregory XVI, the marquis had the honour of informing the assembled cardinals that Louis-Philippe would waive his right of veto, with the assurance that only a wise and virtuous pontiff could be elected by such a wise and virtuous assembly.
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He married in 1849, Anne Mortier of Trévise (1824–1900), granddaughter of marshal Mortier duke of Trévise, who was lady of the Table of Empress Eugenie, and who appeared in the extreme right-hand side of the famous painting of Franz Xaver Winterhalter.
The Musée de l'Ordre de la Libération is a military museum located in the 7th arrondissement at 51 bis boulevard de La Tour-Maubourg, Paris, France.