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Unlike the copper(II) derivative, copper(I) acetylacetonate is an air sensitive oligomeric species.
A Schlenk flask, or Schlenk tube is a reaction vessel typically used in air sensitive chemistry, invented by Wilhelm Schlenk.
After the discovery of ferrocene in 1951, Todd Reynolds and Geoffrey Wilkinson in 1956 synthesized the uranium metallocene Cp3UCl from sodium cyclopentadienide and uranium tetrachloride as a stable but extremely air-sensitive compound.