The octahedron has eight faces, hence the prefix octa. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms.
Material from the Siglio XX Mine, Llallagua, Bolivia, is an unusual pale yellow color, rather than the more common blue or green, forming crusts on quartz and cassiterite, and enclosing crude octahedral jeanbandyite crystals with orange colored shells of plumbogummite.