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The calcium hypothesis for synaptic transmission was directly demonstrated in this synapse by showing that at the equilibrium potential for calcium, no transmitter is released (Bernard Katz and R. Miledi 1967).
Underpotential deposition (UPD) is a phenomenon of electrodeposition of a species (typically reduction of a metal cation to a solid metal) at a potential less negative than the equilibrium (Nernst) potential for the reduction of this metal.