In 2010, Peace was cast as Detective Sergeant Sam Murray in the groundbreaking BBC Three TV series Lip Service, written by Harriet Braun about the loves and lives of group of aged-30-something lesbians in Glasgow, Scotland.
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She is perhaps best known for her role as Sally 'Gracie' Fields in London's Burning from 1998 to 2002, also known for playing Nikki Boston in BBC 1's Waterloo Road
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In 2011, Peace was cast as Head of English, Nikki Boston before being appointed Deputy Headteacher in 2013 for the BBC One school-drama Waterloo Road.
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