He was one of the first American trappers officially allowed into New Mexico, as part of the Glenn-Fowler Expedition of Hugh Glenn and Jacob Fowler.
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He was one of the first trappers to take up formal residence at Taos, New Mexico.
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Slover is known for his association with many other trappers in the American Southwest, including Ewing Young and William Wolfskills working the tributaries of the Colorado River in 1824, and James and Sylvester Pattie on the Gila River in 1828.
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