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In 1833, Leonor was made a Dame of the Order of Saint Isabel, by Amélia of Leuchtenberg, Duchess of Braganza, and a Member of the Order of the Starry Cross, by Caroline Augusta of Bavaria, Empress of Austria.
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Her brother, Pedro de Almeida Portugal, succeeded her father as Marquis of Alorna.
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She often sent her works back to Portugal, most notably a painting entitled Soledade, to her father, and An Alegory of Conjugal Love, to Princess Benedita, wife of José, Prince of Brazil, and a copy of a painting by Guido Reni, to Queen Maria I.