In that role he arranged the marriage of Leopold's daughter Maria Antonia of Austria to Maximilian II Emanuel, Elector of Bavaria in 1685, and settled the dispute between Lorraine and Hungary.
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She married Duke Ferdinand Maria of Bavaria on 5 February 1719 in Reichstadt, Bohemia, a younger son of Elector Maximilian II of Bavaria.
His best works are in the palaces of the Elector of Bavaria, in whose employment he was for several years; among these are several large pictures of the battles fought in HungaryElector
According to Houbraken, who listed him as the most famous pupil of Wybrand de Geest, he was born in Workum and became Kamerling or court painter for the Kurfürst of Vienna.
In 1622, after the capture of Heidelberg by Tilly, when the Protestant Elector of Bavaria Frederick V was supplanted by a Catholic one, the victorious elector Maximilian of Bavaria presented the Palatinate library composed of 196 cases containing about 3500 manuscripts to Pope Gregory.
Junkelmann started to study history at Ludwig Maximilian University of Munich in 1971 and in 1979 he received a PhD for a thesis on the military achievements of Maximilian II (1662–1726) (original title: Kurfürst Max Emanuel von Bayern als Feldherr).
He returned to court for long enough to marry Maria Antonia, daughter of Leopold I, Holy Roman Emperor and Margaret Theresa of Spain, on July 15, 1685 in Vienna, Austria.
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As Governor of the Spanish Netherlands he acquired numerous Dutch and Flemish paintings for the Wittelsbach collection.