Dufief, though a stripling of fifteen, joined in 1792 the royal naval corps assembled under the Charles Hector, comte d'Estaing at Enghien, and went through the campaign with his regiment in the army of the brothers of Louis XVIII until its disbandment.
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During his sojourn in America, he became acquainted with Dr. Joseph Priestley, Thomas Jefferson, and other eminent men.
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His father, a knight of the Order of Saint Louis, served during the revolution as a volunteer under the French princes in Germany; his mother, the Countess Victoire Aimée Libault Gouïn Dufief, was personally engaged in the many battles fought by her relative, General François de Charette, against the revolutionists, for which she was afterwards known as "the heroine of La Vendée".
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