In the December 2006 parliamentary election, Mamboundou was elected to the National Assembly as the UPG candidate in Ndendé constituency, located in the Dola Department of Ngounié Province.
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Mamboundou was elected as Mayor of Ndendé in 1996, and he was also elected to the National Assembly in the December 1996 parliamentary election as a UPG candidate in Ngounié Province.
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