Anna married secondly to Leopold IV, Prince of Lippe, second eldest child of Count Ernst of Lippe-Biesterfeld and his wife Countess Karoline of Wartensleben, on 26 April 1922 in Büdingen.
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Ernst Casimir II, 2nd Prince of Ysenburg and Büdingen
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Anna married firstly to Count Ernst of Lippe-Weissenfeld, sixth child and youngest son of Count Franz of Lippe-Weissenfeld and his wife Baroness Marie of Beschwitz, on 21 November 1911 at Schloss Büdingen in Büdingen.
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