X-Nico

2 unusual facts about Swern oxidation


Swern oxidation

The Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol is oxidized to an aldehyde or ketone using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine.

; Swern, D. title = Structure of the dimethyl sulfoxide-oxalyl chloride reaction product.


Kuwajima Taxol total synthesis

Palladium on carbon hydrogenation removed the benzyl protecting group allowing the Swern oxidation of 2.10 to ketone 2.11


see also