X-Nico

unusual facts about ketone


Ketone

Although ketoacidosis is characteristic of decompensated or untreated type 1 diabetes, ketosis or even ketoacidosis can occur in type 2 diabetes in some circumstances as well.


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Combes quinoline synthesis

It was also observed that increasing the bulk of the R group on the diketone and using methoxy-substituted anilines leads to the formation of 2-CF3-quinolines.

Fries rearrangement

The Fries rearrangement, named for the German chemist Karl Theophil Fries, is a rearrangement reaction of a phenyl ester to a hydroxy aryl ketone by catalysis of Lewis acids.

Jonon

Ionone, a ketone found in violets that contributes to their fragrance

Kuwajima Taxol total synthesis

Palladium on carbon hydrogenation removed the benzyl protecting group allowing the Swern oxidation of 2.10 to ketone 2.11

Parikh–Doering oxidation

The Parikh–Doering oxidation is an oxidation reaction that transforms primary and secondary alcohols into aldehydes and ketones, respectively.

Silicone

F. S. Kipping coined the word "silicone" in 1901 to describe polydiphenylsiloxane by analogy of its formula, Ph2SiO (Ph stands for phenyl, C6H5), with the formula of the ketone benzophenone, Ph2CO.

Swern oxidation

The Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol is oxidized to an aldehyde or ketone using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine.

Torquoselectivity

An example of the latter case is shown below for the torquoselective Nazarov cyclization reaction of a chiral allenyl vinyl ketone.


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