Torrita di Siena borders the following municipalities: Cortona, Montepulciano, Pienza, Sinalunga, Trequanda.
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Trequanda borders the following municipalities: Asciano, Pienza, Rapolano Terme, San Giovanni d'Asso, Sinalunga and Torrita di Siena and consists of the following villages: Trequanda, Castelmuzio and Petroio.