The first demonstration of organic total synthesis was Friedrich Wöhler's synthesis of urea in 1828, which demonstrated that organic molecules can be produced from inorganic precursors, and the first commercialized total synthesis was Gustaf Komppa's synthesis and industrial production of camphor in 1903.
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The Mukaiyama taxol total synthesis published by the group of Teruaki Mukaiyama of the Tokyo University of Science between 1997 and 1999 was the 6th successful taxol total synthesis.
He received his Ph.D. degree working with Professor Dale L. Boger (then at Purdue), completing the first total synthesis of the antitumor agent CC-1065.
Crinine is an alkaloid of the Amaryllidaceae family, and its asymmetric total synthesis was one of the first using the aza-Cope/Mannich reaction.
This reaction was the key step in their total synthesis of norfluorocurarine, a Strychnos alkaloid.