Transient kinetic isotope effects (or fractionation) occur when the reaction leading to isotope fractionation does not follow pure first-order kinetics and therefore isotopic effects cannot be described with the classical equilibrium fractionation equations or with steady-state kinetic fractionation equations (also known as the Rayleigh equation).
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The GEBIK and GEBIF equations are the most generalized approach to describe isotopic effects in any chemical, catalytic reaction and biochemical reactions because they can describe isotopic effects in equilibrium reactions, kinetic chemical reactions and kinetic biochemical reactions.
Isotope | isotope | kinetic energy | Isotope analysis | Transient global amnesia | Rotating radio transient | Palomar Transient Factory | Kinetic isotope effect | Kinetic energy | Isotope separation | isotope geochemistry | Isotope effect | High Energy Transient Explorer | Compact Kinetic Energy Missile |