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He married again in 1672, aged 47, 19 years old Ana Antonia Francisca, (Milán, 14 April 1653 - Madrid, 4 December 1707, aged 50), 4th Marchioness of Caracena, a daughter of Luis de Benavides Carrillo, Marquis of Caracena, 6th marquis of Frómista, Governor of the Duchy of Milan, Governor of the Habsburg Netherlands.