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On 12 May 1879, Therese married George Maximilianovich, 6th Duke of Leuchtenberg (1852–1912), youngest son of Maximilian de Beauharnais, 3rd Duke of Leuchtenberg and his wife Grand Duchess Maria Nikolaevna of Russia.
Upon his father’s death in 1898, Rafail Levitsky continued the operation and tradition of the Levitsky portrait studio taking the now famous photos of Czar Nicholas II and Czarina Alexandra and their children Grand Duchess Olga Nikolaevna of Russia, Grand Duchess Tatiana Nikolaevna of Russia, Grand Duchess Maria Nikolaevna of Russia, Grand Duchess Anastasia Nikolaevna of Russia, and Alexei Nikolaevich, Tsarevich of Russia.