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Princess Maria Amalia of Naples and Sicily
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Prince Alvaro married Carla Parodi-Delfino (Milan, 13 December 1909 – Sanlúcar, 27 July 2000), daughter of Leopoldo Girolamo Parodi-Delfino, Senator of the Kingdom of Italy, and Lucie Henny, on 10 July 1937 at Rome, Italy.
Raffaele was born at Genoa from an aristocratic family, he was a senator of the Kingdom of Sardinia and had the title of Duke of Galliera from 18 September 1838 at the behest of Pope Gregory XVI.