At Marseille he joined the Saint-Domingue expedition, embarking in December accompanied by his wife, who came with him at her own expense in imitation of Pauline Bonaparte, wife of the expedition's commander Leclerc.
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They also worked at Josephine's Château de Malmaison, at the Château de Montgobert for Pauline Bonaparte, and did alterations and decorations for former Bourbon palaces or castles at Compiègne, Saint-Cloud, and Fontainebleau.
The Duke of Parma also usually held the title of Duke of Guastalla from 1735 (when Charles VI, Holy Roman Emperor took it from Mantua) to 1847 (when the territory was ceded to Modena), again, except for the Napoleonic dukes, when Napoleon's sister Pauline was Duchess of Guastalla and of Varella.