In the following years Grosso played in several positions for Real Madrid, even being placed as goalkeeper in the Ramón de Carranza Trophy match with Boca Juniors.
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Even though he shared teams with the likes of Amancio Amaro, Francisco Gento or Ferenc Puskás, Grosso was club top scorer in his first two seasons, scoring 17 goals in 28 games in 1964–65 and 11 in 29 in the following He made his debut in the European Cup on 23 September 1964, netting in the 5–2 away win against Boldklubben 1909.
Mato Grosso | Mato Grosso do Sul | Ramón Vargas | Juan Ramón Jiménez | Ramon Magsaysay | Ramon Magsaysay Award | Ramon Fernandez | Santiago Ramón y Cajal | José Ramón Alexanko | San Ramon, California | Ramon Mitra, Jr. | Ramon Llull | San Ramón | San Ramon | Ramon Berenguer II | Ramón Ayala | San Ramón, Costa Rica | Ramón Ruiz | Ramon Berenguer II, Count of Barcelona | Ramon Berenguer I, Count of Barcelona | José Ramón Florez | Agimat: Ang Mga Alamat ni Ramon Revilla | Ramon "RJ" Jacinto | Ramon Revilla | Ramón Orlando | Ramón Menéndez Pidal | Ramón Luis Rivera | Ramon Jacinto | Ramón Freire | Ramón Emeterio Betances |