Pedini taught himself music from the age of 13, before studying under Fernando Sulpizi at the Perugia Conservatory, Franco Donatoni in Siena and Salvatore Sciarrino in Città di Castello.
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In September 1990 the RAI National Symphony Orchestra conducted by Vittorio Parisi took part in the 42nd Prix Italia in Palermo, playing Pedini's Predica agli Uccelli ("Sermon to the Birds") for soprano, piano, synthesised voice, tape and orchestra on a text by Lucio Lironi and Claudio Novelli.
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