X-Nico

2 unusual facts about Catalysis


Craig L. Hill

Professor Hill’s research encompasses fundamental structural and reactivity studies, Catalysis, functional nanomaterials (Nanotechnology), antiviral chemotherapy and solar energy conversion (Artificial Photosynthesis).

Hairpin ribozyme

It was first identified in the minus strand of the tobacco ringspot virus (TRSV) satellite RNA where it catalyzes self-cleavage and joining (ligation) reactions to process the products of rolling circle virus replication into linear and circular satellite RNA molecules.


Carbonation

Our carbon-based life originates from a carbonation reaction that is most often catalysed by the enzyme RuBisCO.

Cardiff University School of Medicine

A number of Cardiff University staff have been elected as Fellows of the Royal Society, these include Graham Hutchings, professor of Physical Chemistry and Director of the Cardiff Catalysis Institute, School of Chemistry and Professor Ole Holger Petersen, director of Cardiff School of Biosciences.

Catalysis Letters

Catalysis Letters is a peer-reviewed scientific journal covering research on catalysis in a wide range of sub-disciplines such as homogeneous, heterogeneous and enzymatic catalysis.

Colin Eaborn

Thanks to grants from the United States Air Force and Army, Eaborn was able to assemble a team of 15 researchers and students, and in 1960 published the textbook Organosillicon Compounds, which had "a major influence on the development of what has become one of the most prolific areas of organometallic chemistry, with extensive applications in organic synthesis, catalysis and materials science".

Fries rearrangement

The Fries rearrangement, named for the German chemist Karl Theophil Fries, is a rearrangement reaction of a phenyl ester to a hydroxy aryl ketone by catalysis of Lewis acids.

HisB

The hisB gene, found in the enterobacteria (such as E. coli), in Campylobacter jejuni and in Xylella/Xanthomonas encodes a protein involved in catalysis of two step in histidine biosynthesis (the sixth and eight step), namely the bifunctional Imidazoleglycerol-phosphate dehydratase/histidinol-phosphatase.

Joachim Sauer

For a brief time during and after the German reunification (1990–1991) he was the Deputy Technical Director (Catalysis and Sorption) for BIOSYM Technologies, San Diego/USA (now Accelrys).

Koch reaction

Usage of a Ni(CO)4 catalyst with CO and water as a nucleophile is known as the Reppe carbonylation, and there are many variations on this type of metal-mediated carbonylation used in industry, particularly those used by Monsanto and the Cativa processes, which convert methanol to acetic acid using acid catalysts and carbon monoxide in the presence of metal catalysts.

Methylaluminoxane

Natta and Ziegler utilised trimethylaluminium (TMA) as a co-catalyst, and it was not until the mid-1970s that Kaminsky discovered the utility of MAO for catalysis (see Kaminsky catalyst).

Opus 100

Excerpt from The Kinetics of the Reaction Inactivation of Tyrosinase during its Catalysis of the Aerobic Oxidation of Catechol

Pinner reaction

The Pinner reaction (after Adolf Pinner) is an organic reaction of a nitrile with an alcohol under acid catalysis for instance hydrochloric acid.

Stanford Moore

He shared a Nobel Prize in Chemistry in 1972 (with Christian B. Anfinsen and William Howard Stein, for work done at Rockefeller University on the structure of the enzyme ribonuclease and for contributing to the understanding of the connection between the chemical structure and catalytic activity of the ribonuclease molecule.

Transient kinetic isotope fractionation

The GEBIK and GEBIF equations are the most generalized approach to describe isotopic effects in any chemical, catalytic reaction and biochemical reactions because they can describe isotopic effects in equilibrium reactions, kinetic chemical reactions and kinetic biochemical reactions.

Vernon C. Gibson

After gaining a D.Phil. in Malcolm Green's group at Oxford, he went to the California Institute of Technology on a NATO postdoctoral fellowship where he further developed his interest in organometallic chemistry and catalysis with John Bercaw.

Volcano plot

Sabatier principle - a concept in chemical catalysis that relates the optimal concentrations of catalysts and substrates


see also