In August 1814, he was instructed to escort Napoleon's wife, the Empress Marie Louise, to Aix-les-Bains to take the waters.
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Prince Alfred of Montenouvo was born at Vienna, Austrian Empire, only son of William Albert, 1st Prince of Montenuovo (1819–1895), (son of Adam Albert, Count of Neipperg and Archduchess Marie Louise of Austria) and his wife, Countess Juliana Batthyány-Strattmann (1827–1871), (daughter of Count János Baptist Batthyány-Strattmann and Countess Marie Esterházy de Galántha).
The main Neapolitan army, retreating following the disaster at the Battle of Occhiobello, was being pursued by an Austrian corps under the command of Adam Albert von Neipperg.
Count William Albert of Neipperg was born at Parma, Duchy of Parma, son of Adam Albert, Count of Neipperg (1775–1829), by his second wife, Archduchess Marie Louise of Austria (1791–1847), (daughter of Francis II, Holy Roman Emperor and Princess Maria Teresa of Naples and Sicily).